If Nicole Kidman is as loyal to hubby Keith Urban as she is to her stylist, designer L'Wren Scott, Sunday's parents are going to have one long, happy marriage.

The statuesque beauty showed up to tonight's CMA Awards in—surprise!—yet another L'Wren Scott gown straight off the runway. But this time, Nicole added a special accessory: the most amazing push-up bra. Ever.

If we didn't know better, we'd think Nicole was pulling an Amy Winehouse on us. But we're pretty certain her sudden enhancement is only temporary. Still, Keith doesn't seem to mind. Just look at that smile!

Click below to see the other country couple that made us smile in mystyle's Arm Candy Couture gallery!

Last night's sixth-season premiere of Entourage had us believing that Sloan (Emmanuelle Chriqui) and E (Kevin Connolly) were on the road to rekindling their romance—and our inner teeny bopper couldn't be happier!

But the on-again, off-again couple had better hurry up! Jamie-Lynn Sigler, who plays herself on the show, and boyfriend Turtle (Jerry Ferrara) are fast becoming the popular series' cutest couple. In fact, the two have such an amazing onscreen chemistry that they quietly began dating in real life soon after meeting on set. Check them out here celebrating the summer's new episodes in style!

Read more about their red carpet fashion in mystyle's Arm Candy Couture gallery!

Come next Saturday, E! star Kendra Wilkinson will be dressed all in white when she and fiancé Hank Baskett, her baby's daddy, do the wedding march. For now, however, it's about purple. Check out their matchy-matchy look from the L.A. premiere for Tranformers: Revenge of the Fallen. To read more about their red carpet style, go to mystyle's Arm Candy Couture gallery, where you'll find lots of other pairings showing off their couples chic!

We did a double take when Justin Timerlake and Jessica Biel strutted down the red carpet at the Costume Institute Gala last night. Her fashion can be hit or miss, but mostly miss—and he's gone through his own style metamorphosis over the years. Plus, there's the matter of those specs. Is the fashion mogul wannabe channeling Yves Saint Laurent?

Check out more hot couples in mystyle's Arm Candy Couture gallery.

Country music is full of love songs. So it was only appropriate that singing lovebirds flocked to Sunday's Academy of Country Music Awards in Las Vegas. Top New Artist winner Julianne Hough dazzled in a Zuhair Murad gown alongside her country-singer boyfriend and Dancing With the Stars partner, Chuck Wicks. The all-American couple reminded us of a young Tim McGraw and Faith Hill. We're betting on a bright future for these two.

Click below to see more couples that walked the orange carpet at the ACMs in mystyle's newly updated Arm Candy Couture gallery.

Sunday night, while Hollywood (and all of Mumbai!) was busy celebrating the movies, Michelle and Barack Obama held their very first black-tie dinner at the White House. The couple looked so dashingly picture-perfect, we think they should have boarded Air Force One—after begging their guests' forgiveness, of course—and slipped into one of the Oscar after-parties.

To learn more about the Obamas' red carpet style—and to see which couples stood out at the Academy Awards—check out mystyle's Arm Candy Couture gallery.

We confess: We initally created this gallery just so we could show some hunky guys from time to time without having to talk about boring tuxes too much. After all, what is there to say, really? And no, Dev Patel and Freida Pinto from Slumdog Millionaire aren't a couple in real life, as far as we know. But they looked so perfect at the BAFTAs (spoiler ahead!), we're almost willing to believe the movie's perfect love story ending was real. Plus, Freida's dress really does look like candy!

To see what other couple made us ooh and ahh this weekend, go to mystyle's Arm Candy Couture gallery.

Sure, we're still blabbing about the gowns—whose we liked, whose just didn't measure up—but we can't forget the boys. After all, beyond the baubles, the best eye-catching accessory has got to be the hunk on your arm! See who else besides Brad Pitt and Angelina Jolie exuded couples chic at the Golden Globes in our newly updated Arm Candy Couture gallery.